Crystal structure of tricarbonyltris(pyridine-κN)rhenium(I) tetrafluoridoborate
نویسندگان
چکیده
In the title compound, [Re(C6H5N)3(CO)3]BF4, the Re(I) ion is six-coordinated by three pyridine N atoms and three carbonyl C atoms. In each case, the carbonyl C atom lies trans to a pyridine N atom. In the crystal, the ions are linked via C-H⋯F hydrogen bonds and C-H⋯π inter-actions, forming a three-dimensional framework. The F atoms of the BF4 anion are disordered over two positions and gave a final refined occupancy ratio of 0.705 (11):0.295 (11).
منابع مشابه
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عنوان ژورنال:
دوره 71 شماره
صفحات -
تاریخ انتشار 2015